Early solar system aqueous activity: K isotope evidence from Allende

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.     

柱顶层间隔震体系增量动力响应研究

针对悬臂柱顶有拉梁和无拉梁层间隔震体系的抗震性能问题,运用增量动力分析(IDA)方法进行弹塑性分析,模拟结构从弹性到弹塑性直至最后倒塌的全过程。通过调幅地震动得到相应的层间位移角及峰值加速度,分别绘制单条与多条IDA曲线分析拉梁对隔震结构动力响应的影响,研究两种结构的抗震性能。结果表明:在相同性能点,有拉梁和无拉梁对纤维铰弯矩值和曲率值基本无影响,而在不同性能点,纤维铰状态明显不同;两种体系从正常使用阶段到防止倒塌阶段所需的加速度峰值的差距慢慢增大;在极罕遇地震下,柱顶有拉梁层间隔震体系的下部结构抗震性能要高于柱顶无拉梁层间隔震体系。     

Seismic prediction method of multiscale fractured reservoir

Common prestack fracture prediction methods cannot clearly distinguish multiplescale fractures. In this study, we propose a prediction method for macro- and mesoscale fractures based on fracture density distribution in reservoirs. First, we detect the macroscale fractures (larger than 1/4 wavelength) using the multidirectional coherence technique that is based on the curvelet transform and the mesoscale fractures (1/4–1/100 wavelength) using the seismic azimuthal anisotropy technique and prestack attenuation attributes, e.g., frequency attenuation gradient. Then, we combine the obtained fracture density distributions into a map and evaluate the variably scaled fractures. Application of the method to a seismic physical model of a fractured reservoir shows that the method overcomes the problem of discontinuous fracture density distribution generated by the prestack seismic azimuthal anisotropy method, distinguishes the fracture scales, and identifies the fractured zones accurately.     

基于EEMD和ARIMA的海温预测模型研究

类型丰富、时空分辨率高的海洋探测数据,为信号分解和机器学习算法的应用提供了可能。本文针对如何建立有效的海温预测模型这一问题,使用高时空分辨率的海表温度(SST)融合产品,引入信号处理领域的集合经验模态分解(EEMD)和机器学习领域的自回归积分滑动平均模型(ARIMA)。首先利用最适于分解自然信号的EEMD方法,将海温数据分解成多个确定频率的序列;再利用ARIMA分别对各个频率的序列进行预测,最后将各个序列的预测结果进行组合。该方法在丰富数据的支撑下,比以往直接使用海温数据所建立的预测模型精度更高,为更好地进行海温预测提供了新方法。     

南海芋螺科一新记录种(软体动物门, 腹足纲, 新腹足目)

在对中国科学院南海海洋生物标本馆馆藏芋螺科 Conidae 标本, 以及近年来在南海补充采集的标本进行整理的过程中, 通过形态分类学方法鉴定发现隶属于芋螺属 Conus 的中国海新记录种1种: 锈色芋螺 Conus ferrugineus Hwass in Bruguière, 1792, 标本采自西沙群岛。文章描述了该种的外部形态, 查明了其生活习性和地理分布特点, 并与相似种犊纹芋螺 Conus vitulinus Hwass in Bruguière, 1792 进行了比较, 通过壳口内面前沟部位的颜色可将两者区分开: 锈色芋螺呈白色, 而犊纹芋螺呈紫 (褐) 色; 同时对这两个相似种的其他区别特征进行了总结。     

敞开酸溶和偏硼酸锂碱熔ICP-MS法测定多金属矿中的稀土元素及铌钽锆铪

用电感耦合等离子体质谱法(ICP-MS)测定地质样品中的稀土及难熔元素,混合酸敞开酸溶法和碱熔融法是两种主要的溶样方法。但地质样品组分复杂,元素之间存在相互共生的现象,对于特殊元素、特殊样品用传统酸溶法会造成部分元素消解不完全,使测定结果不准确;而碱熔法的操作过程繁琐,且溶液盐度高,易产生基体干扰和堵塞仪器进样系统。本文改进了传统四酸和五酸体系,采用氢氟酸-硝酸-硫酸敞开酸溶体系,用国家一级标准物质制作标准曲线测定15种稀土元素,方法准确度(ΔlgC)为0.001～0.027。同时改进了偏硼酸锂碱熔法,样品用偏硼酸锂碱熔提取,加入氢氧化钠调节溶液至碱性条件,所测元素与偏硼酸锂共沉淀后过滤分离熔剂,再用硝酸复溶测定15种稀土元素及铌钽锆铪。两种溶样方法的测定值与认定值的相对误差为1.09%～9.30%。将混合酸敞开酸溶法测定稀土元素、偏硼酸锂碱熔法测定铌钽锆铪的结果与其他实验室密闭酸溶法相比,两组数据的相对偏差为0.13%～15.32%。本实验表明,混合酸敞开酸溶法适用于测定地质样品中的稀土元素,偏硼酸锂碱熔法不仅适用于测定地质样品中的稀土元素及铌钽锆铪,也适用于测定如古老高压变质岩石及铝含量高的样品中的铌钽锆铪。     

大兴安岭中南段构造岩浆岩带深部地质成矿作用

大兴安岭中南段位于索伦—西拉木伦断裂带与嫩江—白城断裂带交汇域，区内大规模岩浆活动、成矿作用与深部地质活动密切相关。深部地球物理研究成果显示：该区域上地幔存在埋藏较浅的低速、低阻、高热异常体，推断应是深部软流体局部上涌的显示；下地壳存在低密度、低速、高导层，推断是因软流体上涌，诱发下地壳重熔，形成所谓下地壳热流体引起。总之该区域软流层厚度大，热活动性强是引起大规模的岩浆活动及多金属矿床集中分布的深部地质因素。而古生代古亚洲洋洋壳俯冲消减，华北板块、西伯利亚板块陆—陆碰撞拼接及至中生代晚期太平洋板块俯冲作用是引起软流层上涌、下地壳重熔等强烈的壳幔相互作用之源动力。     

基于GRACE RL06数据监测和分析南极冰盖27个流域质量变化

本文基于CSR最新公布的GRACE RL06版本数据,采用Slepian空域反演法估算了南极冰盖27个流域的质量变化.Slepian空域反演法结合了Slepian空间谱集中法和空域反演法的技术优势,能够有效降低GRACE在小区域反演时信号出现的严重泄漏和衰减,进而精确获得南极冰盖在每个流域的质量变化.相对于GRACE RL05版本数据,RL06在条带误差的控制上要更加优化,获得的南极冰盖质量变化时间序列也更加平滑,但在趋势估算上差别并不明显(小于10Gt/a).本文的估算结果显示:在2002年4月至2016年8月期间,整个南极冰盖质量变化速率为-118.6±16.3Gt/a,其中西南极为-142.4±10.5Gt/a,南极半岛为-29.2±2.1Gt/a,东南极则为52.9±8.6Gt/a.南极冰盖损失最大的区域集中在西南极Amundsen Sea Embayment(流域20-23),该地区质量变化速率为-203.5±4.1Gt/a,其次为南极半岛(流域24-27)以及东南极Victoria-Wilkes Land(流域13-15),质量变化速率分别为-29.2±2.1Gt/a和-19.0±4.7Gt/a,其中Amundsen Sea Embayment和南极半岛南部两个地区的冰排放呈现加速状态.南极冰盖质量显著增加的区域主要有西南极的Ellsworth Land(流域1)和Siple Coast(流域18和19)以及东南极的Coats-Queen Maud-Enderby Land(流域3-8),三个地区质量变化速率分别为17.2±2.4Gt/a、43.9±1.9Gt/a和62.7±3.8Gt/a,质量增加大多来自降雪累积,比如:Coats-Queen Maud-Enderby Land在2009年和2011年发生的大规模降雪事件,但也有来自冰川的增厚,如:Siple Coast地区Kamb冰流的持续加厚.此外,对GRACE估算的南极冰盖质量变化年际信号进行初步分析发现,GRACE年际信号与气候模型估算的冰盖表面质量平衡年际信号存在显著的线性相关关系,但与主要影响南极气候年际变化的气候事件之间却不存在线性相关关系,这说明南极冰盖质量变化的年际信号主要受冰盖表面质量平衡的支配,而气候事件对冰盖表面质量平衡的影响可能是复杂的非线性耦合过程.     

Application of Avaatech X-ray fluorescence core-scanning in Sr/Ca analysis of speleothems

Application of X-ray fluorescence core-scanning(XRF-CS) on both marine and lake sediments has achieved remarkable results. However, its application has not been widely extended to the research on speleothems. In this study, we measure the Sr abundance and the Sr/Ca ratios of three stalagmites(two aragonite stalagmites, one calcite stalagmite) using the state-of-the-art fourth-generation Avaatech high-resolution XRF core scanner. Through comparisons among different scan paths and among different scan resolutions, as well as comparisons with inductively coupled plasma optical emission spectrometer(ICP-OES), Itrax XRF, and Artax XRF results, we confirm that the Avaatech XRF core scanner could precisely, quickly, and nondestructively analyze the high-resolution Sr abundance of speleothems. Furthermore, we combine the stalagmite δ~(18)O records to explore the paleoclimatic significance of the measured stalagmite Sr/Ca.     

太行山南端浅层速度结构成像和隐伏断裂探测

利用太行山南端的深地震反射剖面数据，运用初至波层析成像方法反演得到该区域的浅层P波速度结构和基底面展布形态，发现剖面浅部的P波速度变化与沉积盖层厚度和断裂分布有着较好的对应关系。利用跨断裂完成的浅层地震反射剖面，对区域内2条第四纪隐伏活动断裂进行高分辨率成像。结果表明，汤西断裂为东倾的正断层，控制汤阴地堑的西边界，活动年代为中更新世；汤东断裂为西倾的正断层，是汤阴地堑的主控边界断裂，活动年代为晚更新世。